I would love to get a Bufo Alvaris toad, but I sure as hell wouldn't try to get high off of its venom. In fact, I would take pride in the fact that I was saving it from potentially becoming the property of somebody that would intentionally scare it just to make it produce drugs. Now, if by some chance the toad just got scared anyways, by a situation that wasn't caused by me -- and there was a bit of venom that I could somehow collect, I might give a try to smoking it.
But I think some people are underestimating the coolness of just having a pet that naturally makes complexly-substituted tryptamines -- you don't have to scare it and make it produce drugs for you for it to be a cool pet, for chrissakes -- it would be a cool thing just to have and take care of.
I already have a cat, though, and I'm pretty sure my cat would at least try to eat the toad -- which wouldn't be a good situation for my beloved cat or the aforementioned toad. So, no toad for me.