Limpet_Chicken
Bluelighter
Davestate-you mean the domicile of a hymenopteran species winged outside of the mating season and to which the word 'apis' would not apply? if so, yes, and to be honest until some 4-DMAP is available reaction of the acyl halide with either an alkali metal carboxylate and acyl halide or acyl halide and zinc carboxylate in toluene at about 40 'C followed by fractional distillation to separate any unreacted acyl halide, or alternatively aqueous hydrolysis in the presence of a base like potassium carbonate since the acyl halides are MUCH more reactive than the corresponding acyl acid anhydride. (thinking a combination of 4-DMAP for its rapid, room temperature catalysis of acylation and pyrrolidine to regenerate the 4-DMAP)
Ever been in the same room as a bottle of say, benzoyl chloride, propionyl chloride or the like? you don't want to, not without a mask and goggles at the least, they fume off HCl like a bitch (although benzoyl chloride at least, doesn't stink, like propionyl chloride does. That stuff smells rank, like sweaty, dead goat, benzoyl chloride, behind the HCl tang at least has a faint pleasant marzipan smell to it rather than just plain foetid
)
Ever been in the same room as a bottle of say, benzoyl chloride, propionyl chloride or the like? you don't want to, not without a mask and goggles at the least, they fume off HCl like a bitch (although benzoyl chloride at least, doesn't stink, like propionyl chloride does. That stuff smells rank, like sweaty, dead goat, benzoyl chloride, behind the HCl tang at least has a faint pleasant marzipan smell to it rather than just plain foetid
