Especially if it's your first time rolling, I'll echo everyone else and say no. Driving while rolling is always a bad idea, but it's an especially bad idea when the drug is new to you and you can't know the effect it will have on you.
That being said, I have driven while rolling, though not while peaking. One time I overestimated the time a pill would take to come up and it started hitting me while I was on my way home, which was a little scary, but thankfully I was only a few blocks away.