I have known people that have done DMT with hardly any previous psychedelic experience, and they loved it in a profound way....
I am going to make a suggestion towards DMT....
Roll it up with some cannabis, about 30mg per head smoking it.
It vaporises as you smoke, you can smoke until you get as far as you wish to go.
It isn't all at once and like being shot out of a cannon.... There is definitely a drastic change of head-space but its a lot more gradual this way.
LSD is a wonderful psychedelic in its own right, but DMT has always just felt very natural to me. It feels like it belongs, wrapping you in an invisible blanket of warm sensation and euphoria....
I think people are a little bit over cautious in general about DMT... It usually is not a scary experience by a long shot.... I am not saying that you shouldn't respect it, as much as I am saying that DMT isn't something to fear out of its power. It is a compound that seems to reciprocate the level of respect you show it. In the moments before going far with it, state a purpose as to what you wish to gain from it.
DMT is a lot like a loaded gun in that you can very easily take a moment to aim before you shoot it.
LSD is a lot more intimidating in my opinion. Its pretty utterly beautiful, and there is a lot of potential for awesome there, but DMT is easier on the mind and body....
If you do DMT, and I mean like a breakthrough amount, I find its easiest to sandwhich it between a little bit of weed on both sides in a straight bat pipe, and heat the bat until it melts into the herb. Then pack it down a little, clear my head, and smoke.
That being said, my first acid trip killed 3 years of depression in one night....
If you do DMT, and find yourself comfortable doing it alone.... I really suggest that you try it. DMT is a deeply personal and spiritual experience that is much more deeply explored in the privacy of one's room... Do it naked with some soft psychedelic music playing for ambient noise laying in your bed.....
Words can't do this experience justice....