No.
It will of course be an enjoyable high, but it does not magically increase the bioavailability.
There are many ways of potentiating opi's. Dxm, anti-histamines (diphenhydramine, doxylamine, promethazine etc). If you wander over to OD there is an entire mega-thread on potentiating opiates.
Only way you'll increase/change the bioavailability is by changing your route of administration.