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N&PD Moderators: Skorpio
🌟🌟 Social 🌟🌟 Rectify's molecular poetry thread
- Thread starter Dresden
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Rectify
Bluelighter
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Looking Down The Barrel Of A Gun, Son Of A Gun, Son Of A Bitch, Getting Paid, Getting RICH.
People Go Behind My Back, And They Try To Talk Shit. Man, I Was Breaking Records While You Was Sucking Your Mother's DICK.
Beastie Boys, "Paul's Boutique." (1989)
Ask For Janice.
Rectify
Bluelighter
- Joined
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I Dedicate This Song To Felicia Ann Noriega Vasquez. She Always Told Me She Felt Like Eminem Was Singing To HER Through This Song. It Goes, "Just Sit Your Drunk Ass On That Fucking Runway, Hoe! Bitch, You Make Me Hurl."
Felicia Slept With Rick Landrine AND ATL.
Rectify
Bluelighter
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#26 LSD-025 pages 490 to 491 from TiHKAL by Alexander & Ann Shulgin (Transform Press)
ISBN 13: 978-0-9630096-9-9
SYNTHESIS: A solution of 6.7 g KOH in 100 mL H2O, under a He atmosphere and magnetically stirred with a stir bar and hotplate was brought to 75 degrees Celsius, and 10 gram ergotamine tartrate (or vincristine) was added. The reaction mixture turned yellow as the ergotamine went into solution over the course of 1 hour. The stirring was continued for an additional 3 hours. The reaction was cooled to about 10 degrees Celsius [F = (9/5)C + 32] with an external ice bath, and acidified to a pH of 3.0 by dropwise addition of 2.5 N (normal; mol solute per 1000 grams of H2O solvent) H2SO4 pellets. White solids began to precipitate out early in the neutralization titration; approximately 60 mL of sulfuric acid was required. The reaction mixture was chilled overnight in the ice bath, the solid white precipitate was removed by filtration, and the filter cake washed with 10 mL diethyl ether (or THF). The solids were desiccated underneath a heat lamp, and the dry solids were transferred to a Erlenmeyer beaker, suspended in 50 mL 15% anhydrous :NH3 ammonia in MgSO4 dried anhydrous CH3CH2OH (ethyl alcohol), magnetically stirred for 1 hour, and separated by decantation with a separator funnel. The A/B (acid base) extraction was repeated, and the original decantation and the second extract combined and filtered to remove a few hundred milligrams of unwanted solids. The clear filtrate was stripped of the alcoholic solvent under vacuum using a Roto Vap "LaBTop" brand machine. The residual solids were dissolved in 50 mL of 1% aqueous anhydrous ammonia (or ammonium nitrate in a pinch), and the solution was acidified as before with 2.5 N H2SO4. The precipitated solids were removed by filtration using a Buchner funnel and washed with ether until free of color. After drying under vacuum to a constant weight, there was obtained 3.5 grams of dextro LSA lysergic acid hydrate ("dot H2O") which should be stored in a dark, sealed amber glass walled container.
A suspension of 3.15 grams of d-LSA hydrate and 7.1 grams of diethylamine from the hydrolysis of pure or nearly pure OFF! brand insect repellent from the "Family Company" Proctor & Gamble in 150 mL CHCl3 chloroform was brought to a reflux with stirring. With the external heating removed, there was added 3.4 grams of (P=O)Cl3 phosphorus (V) oxy chloride over the course of 2 minutes using a separatory funnel to maintain a slow and constant drip rate, and also at a rate constant enough to maintain sufficient refluxing. The mixture was then held at reflux for an additional 5 minutes until all the solids had dissolved into the solution. After returning to room temperature (20 degrees Celsius), the solution was added to 200 mL of 1 Normal (N) ammonium hydroxide (aqueous ammonia). The 2 phases were separated using a Pyrex separatory funnel, and the organic phase was dried over anhydrous Epsom Salts MgSO4 which had been desiccated in an oven at 450 degrees Fahrenheit for 2 or more hours after being spread out over a pan. Next, the solvent was removed using the Roto Vap brand vacuum distillation apparatus. The residue was HPLC high pressure liquid chromatographed over alumina with fluid elution utilizing a 3 : 1 benzene to chloroform (or CH2Cl2 methylene chloride, probably) mixture, and the collected fraction stripped of solvent under hard vacuum to a constant weight. The freebase solid was recrystallized from a minimum amount of hot, boiling benzene C6H6 to give white crystals with a Mel Temp brand melting point apparatus melting point range of 87 to 92 degrees Celsius. LSD-025 Freebase Rocks.
These crystals were dissolved in warm, dry CH3OH methanol using 4 mL (or about 4 grams, where the rule of thumb is that one mL (gram) of liquid usually makes twenty 50 mg drops each if the density of the liquid being droppered has a very similar density to that of H2O water (about 1.00 grams per mL)). To that solution was added dry dextrotatory tartaric acid acid (0.232 grams per gram of LSD freebase), and the clear, warm solution treated with ether (Et20 diethyl ether or THF tetrahydrofuran) dropwise using a medicinal dropper UNTIL the cloudiness did not dispel with continuous stirring. This opaqueness set to a fine crystalline suspension while preferably using a seed crystal to initiate crystal lattice formation, and the solution was allowed to crystallize overnight in the refrigerator with a paraffin sheet sealing closed the amber glass vial. These steps should be undertaken in complete darkness, such as in a photo developer room. Using a Buchner funnel, the product was removed with vacuum, first washed sparingly with cold, dry MeOH aka methanol aka CH3OH, then washed sparingly with a 1:1 ratio of CH3OH methanol to diethyl ether CH3CH2OCH2CH3 aka Et2O. THF would probably work just as well as Et2O there. The "dry goods" were then dried underneath a heat lamp (a warm incandescent light bulb with crystals spread out over filter paper in close proximity to the light bulb). The white, crystalline powder was indeed d-LSD-O25 tartrate with 2 molecules of hydration H20, had a Mel Temp melting point of 200 degrees Celsius with decomposition of product, and weighed 3.11 grams, giving percent yield of 66%. All of this, mostly, should be carried out in a well ventilated clean room.
1 gram makes 10,000 one hundred microgram hits @ a retail price of $10 USD per dose.Last edited:
