You can distill acetone from nail polish remover fairly easily; you just need a one-litre round-bottom flask, a splashhead and a Leibig condenser (or even better, a Davy condenser, which has a double water jacket). As long as you are heating electrically, the apparatus can be open to the atmosphere. It may still contain water, though; you would have to mix it with something hydrophobic, run off using a separating funnel and distill again. Watch out for azeotropic mixtures, though. You might need to use a fractionating column between the flask and condenser.
This is, of course, not synthesis discussion; it's analysis discussion. Which is as different as putting together and taking apart ......