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Dresden's Chemical Fluff Thread (Name-A-Molecule)

1-(4-isopropylphenyl)-methanone.png


1-(4-isopropylphenyl)-methanone

from cumin

1-(4-isopropylphenyl)-2-aminopropane.png


FRISKIES
1-(4-isopropylphenyl)-2-aminopropane
 
1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane.png


TACOCAT
1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane

1-(3,4-methylenedioxyphenyl)-1-piperazinylmethane.png


RACECAR
1-(3,4-methylenedioxyphenyl)-1-piperazinylmethane
 
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More Wonderful Scents

toluene.png


toluene

4-methyl-2-methoxy-phenol.png


4-methyl-2-methoxy-phenol

1,2-methylenedioxy-3-methoxy-5-methylbenzene.png


1,2-methylenedioxy-3-methoxy-5-methylbenzene

1-methoxy-4-methylbenzene.png


1-methoxy-4-methylbenzene

1,2,3-trimethoxy-5-methyl-benzene.png


1,2,3-trimethoxy-5-methyl-benzene

1,2-dihydroxy-4-methylbenzene.png


1,2-dihydroxy-4-methylbenzene

From The Friedel-Crafts Acylation Of The Parent Benzene Using AlCl3 And Acetyl Chloride.

acetophenone.png


acetophenone

1-(1-oxoethyl)-3-methoxy-4-hydroxybenzene.png


1-(1-oxoethyl)-3-methoxy-4-hydroxybenzene

1-(1-oxoethyl)-3,4-methylenedioxybenzene.png


1-(1-oxoethyl)-3,4-methylenedioxybenzene

1-(1-oxoethyl)-4-methoxybenzene.png


1-(1-oxoethyl)-4-methoxybenzene

1-(1-oxoethyl)-naphthalene.png


1-(1-oxoethyl)-naphthalene

Escrito por

1-phenyl-2-aminopropane.png


AMP
1-phenyl-2-aminopropane

Marzo 26th, 2024 Anno Domini.
 
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N-allyl-1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane.png


JORGE
N-allyl-1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane

1-(4-isopropylphenyl)-2-methylamino-1-carbomethoxypropane.png


JAIME
1-(4-isopropylphenyl)-2-methylamino-1-carbomethoxypropane

allyl%20amine.png


MEL
allyl amine

N-allyl-1-phenyl-1-carbomethoxy-2-aminopropane.png


PHOEBUS_APOLLO_19_(me)
N-allyl-1-phenyl-1-carbomethoxy-2-aminopropane

1-(3,5-dimethoxy-4-isopropylphenyl)-2-aminoethane.png


SAM_"HOMER"_PENNINGTON
1-(3,5-dimethoxy-4-isopropylphenyl)-2-aminoethane

1-(3,4,5-trimethoxyphenyl)-1-carbomethoxy-2-aminoethane.png


FRED_FLINTSTONE
1-(3,4,5-trimethoxyphenyl)-1-carbomethoxy-2-aminoethane

I admit I'm slightly stumped on how one would make those last 2, but this next one is makeable, I know, and so worth it.

1-(3,5-dimethoxy-4-pentylphenyl)-2-aminopropane.png


DJ_ORGANIK
1-(3,5-dimethoxy-4-pentylphenyl)-2-aminopropane
 
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Mini Trip Report: with 3 hits of TACOCAT: "The Euphoria Is Real, And So Am I."
 
SWIM needs 12 more doses of TACOCAT.
It seems to be killing of SWIM's latent syphilis.
 
There's No Denying The Power Of This

1-(4-methylphenyl)-1-carbomethoxy-2-aminopropane.png


KRYSTAL with a K
1-(4-methylphenyl)-1-carbomethoxy-2-aminopropane

CH3CH2CH2CH2CH2-OH
n-amyl alcohol

1-phenyl-1-decanoxy-2-methylaminopropane.png


MARILYN_VOS_SAVANT
1-phenyl-1-decanoxy-2-methylaminopropane
 
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1,3-benzodioxole.png


1,3-benzodioxole, an acidic arene

CH3(C=O)CH3
acetone

Br2

CH3(C=O)CH2-Br
bromoacetone

FeBr3, a Lewis acid

piperonyl%20methyl%20ketone.png


PMK
piperonyl methyl ketone

Starting with benzene gives poor yields because that ring is not actived by the 2 oxygens of 1,3-BDO.
 
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1-phenyl-1-carbophenoxy-2-methylaminopropane.png


ASHTON
1-phenyl-1-carbophenoxy-2-methylaminopropane

1-phenyl-1-carbophenoxy-1-(2-piperidinyl)-methane.png


RIHANNA
1-phenyl-1-carbophenoxy-1-(2-piperidinyl)-methane

1-phenyl-1-(1-oxa-2-oxo-2-phenylethyl)-2-methylaminopropane.png


COCA_PSEUDA
1-phenyl-1-(1-oxa-2-oxo-2-phenylethyl)-2-methylaminopropane

from ephedrine and sodium phenylcarboxylate

1-phenyl-1-phenoxy-2-methylaminopropane.png


AUSTIN
1-phenyl-1-phenoxy-2-methylaminopropane

from ephedrine and sodium phenoxide

2-methylamino-3-(1-oxa-2-oxo-2-phenylethyl)-propane.png


BOLIVIAN_MARCHING_POWDER
2-methylamino-3-(1-oxa-2-oxo-2-phenylethyl)-propane

2-methylamino-3-(1-oxa-2-oxo-2-phenylethyl)-3-carbomethoxy-propane.png


PERUVIAN_FLAKE
2-methylamino-3-(1-oxa-2-oxo-2-phenylethyl)-3-carbomethoxy-propane

2-methylamino-3-carbomethoxy-propane.png


FISHSCALE
2-methylamino-3-carbomethoxy-propane
 
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1-(3,4-dihydroxyphenyl)-1-hydroxy-2-oxopropane.png


1-(3,4-dihydroxyphenyl)-1-hydroxy-2-oxopropane

1-(3,4-dihydroxyphenyl)-1-chloro-2-oxopropane.png


1-(3,4-dihydroxyphenyl)-1-chloro-2-oxopropane

1-(3,4-dihydroxyphenyl)-1-cyano-2-oxopropane.png


1-(3,4-dihydroxyphenyl)-1-cyano-2-oxopropane

1-(3,4-dihydroxyphenyl)-1-carboxy-2-oxopropane.png


1-(3,4-dihydroxyphenyl)-1-carboxy-2-oxopropane

CH2Cl2 / KOH

1-(3,4-methylenedioxyphenyl)-1-carboxy-2-oxopropane.png


1-(3,4-methylenedioxyphenyl)-1-carboxy-2-oxopropane

1-(3,4-methylenedioxyphenyl)-1-carboxy-2-methylamino-propane.png


1-(3,4-methylenedioxyphenyl)-1-carboxy-2-methylamino-propane

1-(3,4-methylenedioxyphenyl)-1-carbmethoxy-2-methylamino-propane.png


THE_L.O.V.E_DRUG in 6 Steps
1-(3,4-methylenedioxyphenyl)-1-carbomethoxy-2-methylamino-propane

This Synthetic Outline Cleverly Avoids The Harsh Reaction Conditions (either H+ or -OH with heat in reflux) Which Could Destroy The Acetal But Which Are Required For The Reaction Of An R-Cyano Functional Group To An R-CO2H Functional Group.
 
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Fun With Benzyl Piperazines!

1-(3,4-methylenedioxy-5-methoxyphenyl)-1-piperazinylmethane.png


OLLIE
1-(3,4-methylenedioxy-5-methoxyphenyl)-1-piperazinylmethane

Starting with

3,4-methylenedioxy-5-methoxy-1-allylbenzene.png


3,4-methylenedioxy-5-methoxy-1-allylbenzene, from essential oil of nutmeg

KMnO4, hot, acidic.

1-carboxy-3,4-methylenedioxy-5-methoxybenzene.png


3,4-methylenedioxy-5-methoxy-1-(chloroformyl)-benzene.png


1-(3,4-methylenedioxy-5-methoxyphenyl)-1-piperazinylmethanone.png


Then Wolff-Kishner the benzylic carbonyl.
 
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1-(3,4,5-trimethoxyphenyl)-1-piperazinylmethane.png


FREDERICK
1-(3,4,5-trimethoxyphenyl)-1-piperazinylmethane

1-(4-methoxyphenyl)-1-piperazinyl-methane.png


JENNIFER
1-(4-methoxyphenyl)-1-piperazinyl-methane

1-(3,4-methylenedioxy-6-methoxyphenyl)-1-piperazinylmethane.png


RAZ_BERRY
1-(3,4-methylenedioxy-6-methoxyphenyl)-1-piperazinylmethane

6:22 pm EST Friday Night Quitting Time.
April the 5th, 2024 Anno Domini.

Okay, just one more.

1-(4-methyl-2,5-dimethoxyphenyl)-1-piperazinyl-methane.png


DEBORAH_DEBBIE_DEB
1-(4-methyl-2,5-dimethoxyphenyl)-1-piperazinyl-methane

Starting with

2,5-dimethoxybenzaldehyde.png

2,5-dimethoxybenzaldehyde

Reduction

2,5-dimethoxytoluene.png


Aromatic carbonylation

4-methyl-2,5-dimethoxybenzaldehyde.png


Reductive Amination With Piperazine

&

Viola!
 
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1-(4-bromo-2,5-dimethoxyphenyl)-1-piperazinylmethane.png


TONY_FALINE_PENNINGTON
1-(4-bromo-2,5-dimethoxyphenyl)-1-piperazinylmethane

1,4-dihydroxybenzene --> 1,4-dimethoxybenzene etc.
 
1-phenyl-1-piperazinylmethanone.png


UNO EIN UNE
1-phenyl-1-piperazinylmethanone

1-(3,4-methylenedioxy-5-methoxyphenyl)-1-piperazinylmethanone.png


DOS
1-(3,4-methylenedioxy-5-methoxyphenyl)-1-piperazinylmethanone

1-(3,4,5-trimethoxyphenyl)-1-piperazinylmethanone.png


TRES
1-(3,4,5-trimethoxyphenyl)-1-piperazinylmethanone

1-(3,4-methylenedioxyphenyl)-1-piperazinylmethanone.png


QUATTRO
1-(3,4-methylenedioxyphenyl)-1-piperazinylmethanone
 
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1-phenyl-1-piperazinylmethanone.png


111
1-phenyl-1-piperazinylmethanone

NaBH4

1-phenyl-1-piperazinylmethanol.png

1-phenyl-1-piperazinylmethanol

1-phenyl-1-piperazinyl-1-chloromethane.png

1-phenyl-1-piperazinyl-1-chloromethane

1-phenyl-1-piperazinyl-1-cyanomethane.png

1-phenyl-1-piperazinyl-1-cyanomethane

1-phenyl-1-carboxy-1-piperazinylmethane.png

1-phenyl-1-carboxy-1-piperazinylmethane

1-phenyl-1-piperazinyl-1-carbomethoxymethane.png


SPEEDY_CINCO
1-phenyl-1-piperazinyl-1-carbomethoxymethane

I actually think this one may be fun.
 
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Rectify said:
This Synthetic Outline Cleverly Avoids The Harsh Reaction Conditions (either H+ or -OH with heat in reflux) Which Could Destroy The Acetal But Which Are Required For The Reaction Of An R-Cyano Functional Group To An R-CO2H Functional Group.
Click to expand...
Looks like it could be finicky near the end, but I like what's going on here.
 
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