Terribly sorry to revive an old off topic conversation, but has anyone here actually considered looking at the clock when comparing the two routes? Sounds easy enough.
That being said, the onset should be sooner when smoked vs. iv'ed (time to first perceived effects), but since the rate at which you administer is lower when smoking it the rush isn't as intense. The peak plasma concentration will also always (!) be lower when smoking a substance because it is a wasteful process, not all of it is evaporated, not all of it is absorbed and for some substances part of the material decomposes. Also, due to the lower rate at which it is administered and the earlier onset when smoking heroin, it should also be cleared from the plasma sooner (e.g. bind to your neurons) which is another reason for lower peak plasma concentration.
Btw whoever said that, the path for all veins (except for pulmonary veins which you cannot reach with a needle) is the same, the jugular vein is a vein still and leads to the heart. However the jugular vein is closer to the heart and blood flow is aided by gravity when sitting or standing which is why a substance will hit you faster when injected into it vs being injected into e.g. the dorsal veins of your foot. Maybe you were thinking of injecting into the carotid artery? I would not encourage anyone to do that lol, however despite the madness such behaviour would require I could imagine it provides quite the rush, even more intense than the aboslutely amazing sounding experience oxyaddict05 had there since in his case the largest portion of the substance isn't carried to the brain so the maximum "safe" (lol) dosages that can be used would have to be lower I think.
As for the OP's claims, Swain has sufficiently explained why smoking is much safer than iv'ing.
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2117615/
sigh... I'd say it was an accident. Despite the article's claims for those carotid injections to have been frequent I'd say she was going for the jugular vein.