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The Shulgins and the N,N-diallyltryptamines...

Deinonychus

Bluelighter
Joined
Oct 20, 2012
Messages
401
Hey everybody! So I've been wondering for a while why Shulgin chose the N,N-diallyltryptamines (DALT, 5-MeO-DALT, their analogues) as the focus of his recent research. It's certainly not fully psychedelic, but that's neither good nor bad, just different compared to the focus of his research in the old days (P and TIHKaL compounds). I know he was going to publish another book about the DALTs, but I don't know what the status of that project is since the good doctor is now very unfortunately suffering physical and mental health issues.

Has anybody ever seen or heard any explanation of the choice of the diallyltryptamines? And if not would anybody like to hazard a guess as to why he picked those and not other more fully psychedelic compounds such as the flies or N-benzyl PEA derivatives?

One thing I can think of is that perhaps he wanted to focus on compounds that he had conceptualizer, instead of just elucidating the activity of Nichols' compounds in more detail. That's not to say that there's any bad blood between them, on the contrary I believe they are well-acquainted, but back to the point perhaps he wanted to explore things that were 'his'? That's just a wild guess, I really don't know.

Is there some sort of SAR that he was aiming for with the diallyltryptamines that is contrary to expectations in the manner of the theoretical island of stability in the superheavy elements? Like a particular substitution of DALT that restores full psychedelia despite the long chains on the nitrogen, analogous to the half-lives of superheavy elements possibly increasing for a few elements due to filled orbitals even though the heaviness should make the half-lives continue to decrease.

Anyway this is just something I've been a bit curious about for a while, so I decided to see if anybody has any answers regarding the motivation for choosing diallyltryptamines for his most recent work. And to be clear, while 5-MeO-DALT sure isn't my thing, since I prefer full psychedelia, I'm not knocking it by claiming it to be less than fully psychedelic. That's just a subjective observation/opinion, not a value judgement.

Cheers
D
 
One thing to note is that in some jurisdictions, the law prohibits tryptamines with N-alkyl substituents, but not N-allyl substituents.
 
To assume that Shulgin made DALT or 5-MEO-DALT a focus of recent research is probably not accurate. It was just one of many that he had in a new book. For 5-MeO-DALT in particular, he gave a copy of the article to Murple who leaked it online, and within weeks it was shipping from China. That's the awesome story behind this not-so-awesome chemical. I'm sure people have found some interesting uses for 5-MeO-DALT, but aside from something that gets you kinda oddly stoned, I can't imagine what those uses would be.
 
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