If a methylenedioxy chemical is present in your urine in a decent amount, then marquis and mandelin will turn black. But I am basing this off how safrole and isosafrole turn these testers instant dark black with very small amounts. isosafrole is 1,2-methylenedioxy-propenylbenzene, so it could be turning black over a number of other reasons too. Try your urine test and tell us how it goes.