Rectify's molecular poetry thread

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CHRISTOPHER
1-(2,4,6-trimethoxy-3,5-dibromophenyl)-2-aminopropane; tma-6 / Br2 / FeBr3

Bromo phenyls are ring deactivating, while methoxies are activating. Should feel kind of like a speedball (a strong upper mixed with a strong downer).

 

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CH3CH2-Br

--> Wacker --> ammonium formate Leuckart, etc.

C_LOVE
1-(3-methoxy-4-ethoxyphenyl)-2-aminopropane

 

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REX
1-phenyl-1-carbomethoxy-2-methylaminopropane

My best idea yet. Pricey, but worth it.

 

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OXO-PRELUDIN
1-aza-2-methyl-3-phenyl-4-oxa-5-oxo-cyclohexane

I really have no clue how to synthesize this lactone, to be perfectly honest. Okay, here goes my best guess.

PPA
1-phenyl-1-hydroxy-2-aminopropane

1,2-dichloro-1-oxoethane

I dunno. Something like that.

 

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Similarly,

1-(3,4-methylenedioxyphenyl)-1-hydroxy-2-aminopropane (from MDC)

Cl-CH2(C=O)-Cl

SANTA_MONICA_HIGH_ROLLER
1-aza-2-methyl-3-(3,4-methylenedioxyphenyl)-4-oxa-5-oxo-cyclohexane

 

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THIN_MINTS
1-(3,4-methylenedioxyphenyl)-2-aminopropane

Raver Amy's Favorite!

 

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MI_PARFUM_CHIMICA_MOOY_ESPECIAL
1-methyl-3,4-methylenedioxybenzene

 

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1-allyl-3,4-methylenedioxybenzene

1-(propenyl)-3,4-methylenedioxybenzene

1-(3,4-methylenedioxyphenyl)-methanone

MI_PARFUM
1-methyl-3,4-methylenedioxybenzene

 

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MARCO_POLO
1-(4-pyridinyl)-2-methylaminopropane

Everything All The Time.

 

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1-(4-isopropylphenyl)-methanone

from cumin

FRISKIES
1-(4-isopropylphenyl)-2-aminopropane

 

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TACOCAT
1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane

RACECAR
1-(3,4-methylenedioxyphenyl)-1-piperazinylmethane

 

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Protocol solves ‘malleability problem’ of activating alkali metals like sodium https://www.chemistryworld.com/news...w_shared&utm_medium=post&utm_source=navigator

 

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More Wonderful Scents

toluene

4-methyl-2-methoxy-phenol

1,2-methylenedioxy-3-methoxy-5-methylbenzene

1-methoxy-4-methylbenzene

1,2,3-trimethoxy-5-methyl-benzene

1,2-dihydroxy-4-methylbenzene

From The Friedel-Crafts Acylation Of The Parent Benzene Using AlCl3 And Acetyl Chloride.

acetophenone

1-(1-oxoethyl)-3-methoxy-4-hydroxybenzene

1-(1-oxoethyl)-3,4-methylenedioxybenzene

1-(1-oxoethyl)-4-methoxybenzene

1-(1-oxoethyl)-naphthalene

Escrito por

AMP
1-phenyl-2-aminopropane

Marzo 26th, 2024 Anno Domini.

 

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JORGE
N-allyl-1-(4-isopropylphenyl)-1-carbomethoxy-2-aminopropane

JAIME
1-(4-isopropylphenyl)-2-methylamino-1-carbomethoxypropane

MEL
allyl amine

PHOEBUS_APOLLO_19_(me)
N-allyl-1-phenyl-1-carbomethoxy-2-aminopropane

SAM_"HOMER"_PENNINGTON
1-(3,5-dimethoxy-4-isopropylphenyl)-2-aminoethane

FRED_FLINTSTONE
1-(3,4,5-trimethoxyphenyl)-1-carbomethoxy-2-aminoethane

I admit I'm slightly stumped on how one would make those last 2, but this next one is makeable, I know, and so worth it.

DJ_ORGANIK
1-(3,5-dimethoxy-4-pentylphenyl)-2-aminopropane

 

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Mini Trip Report: with 3 hits of TACOCAT: "The Euphoria Is Real, And So Am I."

 

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Church Of Christ, Scientist. (COCS)

ALL ARE WELCOME.

 

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SWIM needs 12 more doses of TACOCAT.
It seems to be killing of SWIM's latent syphilis.

 

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Birch reduction

Suppachai Krajangsri on LinkedIn: I have done traditional Birch reaction a lot during PhD. It was fun with…

I have done traditional Birch reaction a lot during PhD. It was fun with Li and Na metals. Mg and Ca would be more practical.

www.linkedin.com

 

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There's No Denying The Power Of This

KRYSTAL with a K
1-(4-methylphenyl)-1-carbomethoxy-2-aminopropane

CH3CH2CH2CH2CH2-OH
n-amyl alcohol

MARILYN_VOS_SAVANT
1-phenyl-1-decanoxy-2-methylaminopropane

 

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1,3-benzodioxole, an acidic arene

CH3(C=O)CH3
acetone

Br2

CH3(C=O)CH2-Br
bromoacetone

FeBr3, a Lewis acid

PMK
piperonyl methyl ketone

Starting with benzene gives poor yields because that ring is not actived by the 2 oxygens of 1,3-BDO.