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Rectify's molecular poetry thread

I've often wondered if this DMT intermediate would do anything on its own?

1-(indole-3-yl)-1,2-dioxo-2-dimethylaminoethane.png
 
1-(2-amino-3,4,5-trimethoxyphenyl)-2-aminoethane.png


YANA
1-(2-amino-3,4,5-trimethoxyphenyl)-2-aminoethane

A Higher Love.
 
(6aR,9R)-N,N-diethyl-7-(1-methyl2-phenylethyl)-4,6,6a,7,8,9-hexahydroindolo-%5b4,3-fg%5d-quinoline-9-carboxamide.png


LSD-AMP
(6aR,9R)-N,N-diethyl-7-(1-methyl-2-phenylethyl)-4,6,6a,7,8,9-hexahydroindolo-[4,3-fg]-quinoline-9-carboxamide

(6aR,9R)-N,N-diethyl-7-(1-methyl-2-(3,4-methylenedioxyphenyl)ethyl)-4,6,6a,7,8,9-hexahydroindolo-%5b4,3-fg%5d-quinoline-9-carboxamide.png


LSD-X
(6aR,9R)-N,N-diethyl-7-(1-methyl-2-(3,4-methylenedioxyphenyl)ethyl)-4,6,6a,7,8,9-hexahydroindolo-[4,3-fg]-quinoline-9-carboxamide

from nor-LSD
 
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chemrxiv.org

Synthesis of N–H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids as Aminating Agent

Herein, we presented a practical methodology for the intermolecular aziridination of alkenes, using HOSA as the aminating agent, alongside pyridine or piperidine as the base, within HFIP solvent system. Notably, this approach showcases excellent reactivity, especially with non-activated alkenes...
chemrxiv.org chemrxiv.org

I'm thinking once you have the N-H aziridine from the arene precursor, it could be opened somehow.
 
(6aR,9R)-N,N-diethyl-7-(1-phenyl-1-cyclohexyl)-4,6,6a,7,8,9-hexahydroindolo-%5b4,3-fg%5d-quinoline-9-carboxamide.png


THE_INCREDIBLE_HULK
(6aR,9R)-N,N-diethyl-7-(1-phenyl-1-cyclohexyl)-4,6,6a,7,8,9-hexahydroindolo-[4,3-fg]-quinoline-9-carboxamide
 
(6aR,9R)-N,N-diethyl-7-(trifluoromethyl)-4,6,6a,7,8,9-hexahydroindolo-%5b4,3-fg%5d-quinoline-9-carboxamide.png


N-TFM-LSD
(6aR,9R)-N,N-diethyl-7-(trifluoromethyl)-4,6,6a,7,8,9-hexahydroindolo-%5b4,3-fg%5d-quinoline-9-carboxamide

1-phenyl-2-(trifluoromethylamino)-propane.png


N-TFM-AMP
1-phenyl-2-(trifluoromethylamino)-propane

1-(3,4-methylenedioxyphenyl)-2-(trifluoromethylamino)-propane.png



N-TFM-MDA
1-(3,4-methylenedioxyphenyl)-2-(trifluoromethylamino)-propane
 
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1-(2-methoxy-4,5-methylenedioxyphenyl)-1-carbomethoxy-2-aminopropane.png


OPEN_SESAME_STREET
1-(2-methoxy-4,5-methylenedioxyphenyl)-1-carbomethoxy-2-aminopropane

-just another one of my thought delicacies
-from sesamol (3,4-methylenedioxyphenol)
 
1-phenyl-1-hydroxy-2-methylaminopropane.png


Cl-(C=O)-Cl

1-phenyl-1-chloro-2-methylaminopropane.png


sodium phenoxide

1-phenyl-1-phenoxy-2-methylaminopropane.png


NOM DE PLUME LE_PENN
1-phenyl-1-phenoxy-2-methylaminopropane
 
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sodium%203,4-methylenedioxyphenoxide.png


sodium 3,4-methylenedioxyphenoxide
from sesamol

1-phenyl-1-hydroxy-2-methylaminopropane.png


1-phenyl-1-chloro-2-methylaminopropane.png


1-phenyl-1-(3,4-methylenedioxyphenoxy)-2-methylaminopropane.png


ASHLEY
1-phenyl-1-(3,4-methylenedioxyphenoxy)-2-methylaminopropane
 
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1-(3,4-methylenedioxyphenyl)-1-oxo-2-methylaminopropane.png


METHYLONE
1-(3,4-methylenedioxyphenyl)-1-oxo-2-methylaminopropane

1-(3,4-methylenedioxyphenyl)-1-hydroxy-2-methylaminopropane.png


1-(3,4-methylenedioxyphenyl)-1-chloro-2-methylaminopropane.png


NaOMe (sodium methoxide)

1-(3,4-methylenedioxyphenyl)-1-methoxy-2-methylaminopropane.png


BATMAN
1-(3,4-methylenedioxyphenyl)-1-methoxy-2-methylaminopropane
 
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O-acetyl-1-phenyl-2-methylamino-1-hydroxypropane.png


G7
O-acetyl-1-phenyl-2-methylamino-1-hydroxypropane

^--ephedrine + acetic andydride

2,4-dioxo-3-oxapentane.png


2,4-dioxo-3-oxapentane

But still. The N needs protecting somehow for that to happen.
 
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From methylone

1-(3,4-methylenedioxyphenyl)-1-phenoxy-2-methylaminopropane.png


WAKE_UP
1-(3,4-methylenedioxyphenyl)-1-phenoxy-2-methylaminopropane

Likewise, starting with methylone using sodium 3,4-MDO-PhenOxide instead of sodium phenoxide:

1-(3,4-methylenedioxyphenoxy)-2-methylamino-1-(3,4-methylenedioxyphenyl)-propane.png


MY_SUPER_SWEET_16
1-(3,4-methylenedioxyphenoxy)-2-methylamino-1-(3,4-methylenedioxyphenyl)-propane

1,1-bis-(3,4-methylenedioxyphenyl)-2-aminopropane.png


BIS_TRIS_TETRAKIS
1,1-bis-(3,4-methylenedioxyphenyl)-2-aminopropane
 
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Ladies & Gentlemen,
It's Time. I Would Like To Present Something...Stronger.

1-(3,4-methylenedioxyphenyl)-1-methoxy-2-methylaminopropane.png


BATMAN
1-(3,4-methylenedioxyphenyl)-1-methoxy-2-methylaminopropane
 
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