Ketamine salts solubility

[sekio]

12 bismuth atoms, sure, but also a thorium atom ?
so it is radioactive as well? (technically bismuth is radioactive as well, just with an obscenely long half life)

also, can we put a methylenedioxy on it somewhere??

 

[polymath]

it's worth a try, is this not the same reaction that can be run in spearmint oil (menthone acting as a catalyst of sorts) ?

Yes, that one, but I recall the decarboxylation catalyst in spearmint oil was actually carvone. Caraway seed oil contains a different stereoisomer of that unsaturated ketone, but should also have the same catalyst effect.

Edit: Looks like the high-boiling solvent in the original Rhodium article was diphenylmethane, not biphenyl as I first thought.

 

[Nagelfar]

…
also, can we put a methylenedioxy on it somewhere??

↑I now just see it replacing the cyclohexane in N-methylamp just as the buckminsterfullerene in the original post of the random molecule doodles thread.

 

[polymath]

The article where this colorful current density plot is from also lists some other curious aromatic rings, including that drawn below:

Does anyone know the name of this molecule? Other aromatics shown in the paper included a six-membered ring of alternating nitrogen and sulfur atoms, and some kind of atomic cluster made from sodium and mercury atoms.

Reading the article, it was excessively difficult to find whether that current density plot was an experimental or theoretical result (seemed to be calculated with density functional theory if I understood correctly).

 

[MsDiz]

The article where this colorful current density plot is from also lists some other curious aromatic rings, including that drawn below:

Does anyone know the name of this molecule? Other aromatics shown in the paper included a six-membered ring of alternating nitrogen and sulfur atoms, and some kind of atomic cluster made from sodium and mercury atoms.

Reading the article, it was excessively difficult to find whether that current density plot was an experimental or theoretical result (seemed to be calculated with density functional theory if I understood correctly).

It a porphyrinogen

 

[polymath]

Thanks, I was surprised to see that it's a biocompound.

 

[MsDiz]

Thanks, I was surprised to see that it's a biocompound.

You can get deep into a proper rabbit hole (reading wise) when it comes to porphyrinogens. Haha.

 

[Rectify]

5-carba-delta-9-THC

If A carbomethoxy [R-(C=O)-O-CH3] group is a bioisostere of a phenyl (R-C6H6) functional group, then this benzene to carbomethoxy analogue of amphetamine may be psychoactive:

AMC
1-carbomethoxy-2-methylaminopropane

NAZAN
3-(2-dimethylaminoethyl)-1-azanaphthaline

Kind of a shot in the dark.

 

[Rectify]

BRANTLEY
1-(2,5-dibromo-3,4-methylenedioxyphenyl)-2-aminopropane

SHANNON
1-(indole-3-yl)-1-piperidinylcyclohexane

SEAMUS
1-(indole-3-yl)-1-piperidinylmethane

 

[Rectify]

Brantley Is Righteous.

 

[Rectify]

ASPIRIL
sodium-2-(2-methoxyphenyl)propionate, racemic

a non steroidial anti inflammatory pain reliever

TEEN SPIRIT
n-tetradecanal

designer fragrance chemical similar to undecanal (found in Chanel No. 5)

TRISOMNIFORE
1,3,5-trihydroxy-2,4,6-triisopropylbenzene

sedative hypnotic anesthetic agent and analogue of propofol

CHLOROEAZE
2,6-diisopropyl-1-chlorobenzene

minor tranquilizer

ECLISPERDAL
3-(1-ethylpiperazin-4-yl)-6-chloroindole

major tranquilizer / antipsychotic

 

[Rectify]

CANNON BROWN
1-(4-bromo-3,5-dimethoxyphenyl)-2-aminopropane

See Bee.

 

[sekio]

porphyrins are part of a lot of cool compounds...
chlorophyll

heme (found in hemoglobin and myoglobin, binds oxygen)

stercobilin (makes your poo brown)

urobilin (makes your pee yellow)

 

[sekio]

ECLISPERDAL
3-(1-ethylpiperazin-4-yl)-6-chloroindole

major tranquilizer / antipsychotic

ref?

 

[Rectify]

^--Purported. (Pure speculation on my part)

MARVIN
1-(3,5-dioxo-4,4-dimethylcyclohexyl)-2-aminopropane

REESE
1-(3-oxo-4,4-dimethylcyclohexyl)-2-methylaminopropane

KRISTEN
1-(3,6-dioxo-4,4-dimethylcyclohexyl)-2-aminopropane

 

[Rectify]

SID_A
13-methoxy-N,N-diethyllysergamide

Oh Lord, Won't You Buy Me A Mercedes Benz?

KID_A
13-methyl-N,N-diethyllysergamide

RIGHT-BRAINED
if you can name this IUPACically, you win a virtual prize (disregard the incorrect extra carbon carbon double bond drawn above)

PEPPERMINT METHAMPHETAMINE
1-(4-isopropyl-3-oxocyclohexyl)-2-methylaminopropane

 

[Rectify]

Leave It To

 

[Nagelfar]

Article on quantum electron/nucleus spin and consciousness

A great quote taking consideration of the peculiar function of anaesthetics:

“The only thing we are sure about consciousness, is that it is soluble in chloroform”

Excerpt:

…What is perhaps more surprising with regards to lithium is that different isotopes have been shown to have differing effects on the mothering behaviour of rats. A similar phenomenon has recently been recorded in the action of xenon, an anaesthetic. Na Li and colleagues at Huazhong University of Science and Technology in Wuhan, China, found that differing isotopes of xenon cause differing levels of unconsciousness (Anesthesiology 129 271). This seems extraordinary, that changing something as small as the spin of a nucleus might result in macroscopic changes on the level of something as complex as the mothering instinct or, indeed, consciousness itself.…

 

[Rectify]

DOPEY
3,6-diacetyl-N-ethyl-morphinan

morningloryseed
lysergamide

NIFTY
diphenylmethylsulfinyl-2-aminopropane

 

[Rectify]

STARLETT
1-(2,6-dichloro-3,4,5-trimethoxyphenyl)-2-aminoethane

BRAMBLETT
1-(2,6-dibromo-3,4,5-trimethoxyphenyl)-2-aminoethane

JOLEN NOEL
1-(2,6-diiodo-3,4,5-trimethoxyphenyl)-2-aminopropane

DANIEL IN THE LION'S DEN
1-(4-propylthio-2-methoxyphenyl)-2-aminopropane

Shadrack Meshack Abendigo